Experimental Data on Nickel-Catalyzed Alkyl Radical Coupling Reactions

21.1 KB of experimental data from figshare, authored by Hao Liang and last updated on 2026-04-27. The dataset likely contains results from the investigation of phenoxy(imine)–nickel(II)–aryl complexes reacting with alkyl radicals to form C–C bonds. It includes evidence from radical clock experiments, competition studies, kinetic isotope effect measurements, and computational analyses.

Use Cases

• Analyzing ligand effects on radical capture and C–C bond formation based on described competition experiments.
• Modeling multistep reaction pathways for C–C bond formation based on radical clock experiment differences.
• Investigating nickel(III) intermediate states based on electron paramagnetic resonance (EPR) spectroscopy data mentioned in the description.
• Correlating computational studies with experimental kinetic isotope effect measurements.

Strengths

• Includes multiple experimental techniques: radical clock, competition, kinetic isotope effect, and EPR spectroscopy.
• Data is associated with peer-reviewed research concepts, suggesting a structured experimental design.
• File size is 21.1 KB, indicating a focused and likely well-defined dataset.

Limitations

• Row count and column definitions are unknown, which limits suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• The dataset's small scale (21.1 KB) may limit the breadth of contained information.

Provenance

Source

figshare, author Hao Liang.

Collection Method

Experimental laboratory data from chemical synthesis and analysis.

Time Range

null

Freshness

Last updated 2026-04-27 20:30:04; freshness should be verified.

Geography

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