Rhodium(III)-Catalyzed C–H Allylation and Cycloaddition Reaction Data

Rhodium(III)-catalyzed C–H functionalization of azomethine imines with vinyl cyclopropanes produces allylated intermediates and tetracyclic N-heterocycles. The dataset, authored by Chaeeun Kim and last updated in June 2026, is a 12 MB ZIP file. Post-transformations of malonate-containing heterocycles highlight the synthetic relevance of the proposed method.

Use Cases

• Validate reaction mechanisms based on the described allylated intermediate formation.
• Design new synthetic routes for indenopyrazolopyrazolones based on the Rh(III) catalysis method.
• Benchmark computational models for [3 + 2] dipolar cycloaddition reactions.
• Explore post-transformation strategies for tetracyclic N-heterocycles containing malonate groups.

Strengths

• The dataset is associated with a specific synthetic method published by Chaeeun Kim.
• The ZIP file size is 12.0 MB, indicating a contained data volume.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.
• The description is focused on the method; the actual data content requires manual inspection.

Provenance

Source

figshare

Freshness

Last updated 2026-06-02 16:11:52; freshness should be verified.