C–H Allylation and Cycloaddition Data Under Rh(III) Catalysis

Chaeeun Kim published a dataset on figshare in June 2026 describing a rhodium(III)-catalyzed C–H functionalization method. The data, stored in a 40.0 MB ZIP file, relates to the synthesis of indenopyrazolopyrazolone compounds via allylation and dipolar cycloaddition reactions. The dataset is licensed under CC-BY-NC-4.0.

Use Cases

• Training reaction prediction models based on the described C–H functionalization and cycloaddition mechanisms.
• Benchmarking computational chemistry methods using data on vinyl cyclopropane and azomethine imine reactivity.
• Analyzing synthetic pathways for malonate-containing tetracyclic N-heterocycles mentioned in the description.

Strengths

• Dataset is 40.0 MB in size, indicating a non-trivial volume of supporting information.
• The description provides a specific mechanistic proposal for the catalytic cycle, offering context for the data.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• Description metadata is limited; actual data quality requires manual inspection after download.

Provenance

Source

Chaeeun Kim via figshare

Collection Method

Likely contains experimental or computational data from the described chemical research.

Freshness

Last updated 2026-06-02 16:11:51; freshness should be verified.