Catalytic Enantioselective Dearomatizing Wittig Rearrangement Data

Tengfei Kang published data on catalytic enantioselective dearomatizing Wittig rearrangements on figshare in May 2026. The dataset likely contains experimental results and computational insights for divergent reaction pathways. The file size is 119.3 KB.

Use Cases

• Analyze enantioselectivity outcomes based on reported enantiomeric ratios (er) up to 98:2.
• Compare solvent-dependent reactivity pathways based on the description of 1,4-dioxane and mesitylene.
• Study reaction mechanisms based on computational DFT studies mentioned in the description.
• Evaluate divergent product formation based on the description of [2,3]-Wittig, [1,2]-Wittig, and Sommelet–Hauser-type products.

Strengths

• Includes stereoselectivity metrics such as enantiomeric ratios (er) up to 98:2 and diastereomeric ratios (dr) up to 94:6.
• Describes solvent-dependent reactivity leading to divergent product types.
• Incorporates computational DFT studies to explain stereocontrol.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.
• The dataset is very small (119.3 KB), indicating limited scope.

Provenance

Source

Tengfei Kang

Collection Method

Likely contains experimental and computational chemistry data from a research project.

Freshness

Last updated 2026-05-25 16:03:30; freshness should be verified.