Cadmium-Based Metal-Organic Framework Structures and Catalytic Activity

Two polynuclear cadmium(II)-based metal-organic framework complexes were synthesized and characterized by Arijit Sadhukhan. Their structures were analyzed using single crystal elemental analysis, X-ray diffraction, thermogravimetric analysis, and density functional theory studies. The dataset includes computational analysis of noncovalent interactions and catalytic performance data for the Knoevenagel condensation reaction.

Use Cases

• Analyzing non-covalent interaction strength and cooperativity effects based on the described DFT, QTAIM, and NCI plot analyses.
• Comparing catalytic efficacy for condensation reactions based on the described room-temperature Knoevenagel condensation tests.
• Studying the relationship between 3D polymeric network architecture and material stability based on the described structural characterization and recyclability tests.

Strengths

• Includes multiple characterization methods: single crystal analysis, X-ray diffraction, thermogravimetric analysis, and DFT studies.
• Catalytic stability is demonstrated, with complex 1 being recyclable for up to four cycles with comparable activity.
• File size is 563.3 KB, indicating a focused and likely well-defined dataset.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• Description metadata is limited; actual data quality requires manual inspection after download.

Provenance

Source

figshare

Collection Method

Synthetic and computational characterization of two metal-organic framework complexes.

Time Range

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Freshness

Last updated 2026-05-14 06:45:38; freshness should be verified.

Geography

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