Copper-Photocatalyzed Enantioselective S-Alkylation Data

3.8 MB of CIF files from a study on enantioselective S-alkylation of sulfenamides. The dataset, authored by Xiangyu Zhuang and last updated in March 2026, contains results from a copper-photoredox catalysis method using amino-acid-derived ligands. The work demonstrates the synthesis of chiral sulfilimines from alkyl carboxylic acids and iodides.

Use Cases

• Validate computational models of copper-sulfenamide intermediates based on mechanistic studies mentioned.
• Analyze reaction scope based on the described tolerance of primary, secondary, and tertiary alkyl radicals.
• Support method development for synthesizing sulfoximines based on the described downstream oxidation utility.

Strengths

• Data is associated with a specific, peer-reviewed synthetic methodology described in detail.
• The 3.8 MB CIF file format suggests structured, machine-readable crystallographic or chemical data.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.

Provenance

Source

figshare, author Xiangyu Zhuang.

Collection Method

Likely contains experimental results from the described copper-photoredox catalysis study.

Freshness

Last updated 2026-03-26 02:29:39; freshness should be verified.