Cyaphide Complexes of Rare-Earth Metals and Their Tetramerization

Synthesis data for rare-earth metallocene complexes bearing the cyaphide ligand. The dataset, 91.9 KB in size, was authored by Tajrian Chowdhury and last updated on April 23, 2026. It details the synthesis of monomeric and tetrameric complexes, with the ionic radius of the rare-earth ion influencing the solution-phase speciation.

Use Cases

• Modeling the tetramerization reaction mechanism based on the described computational probing.
• Analyzing the relationship between rare-earth ionic radius and complex stability mentioned in the description.
• Studying the formation of the unprecedented [PCC–PP–CCP]⁴⁻ motif in oligomers.
• Investigating cyaphide ligand transfer and coordination chemistry in metallocene systems.

Strengths

• Dataset is openly shared under a CC-BY-NC-4.0 license.
• Description provides specific chemical synthesis pathways and observed species.
• Includes computational insights into a unique tetramerization reaction mechanism.

Limitations

• Dataset size is 91.9 KB, indicating a very limited scope.
• Row count and column-level documentation are unknown.
• Data format is listed as XYZ, which may require specific tools for interpretation.

Provenance

Source

figshare

Collection Method

Synthesized through salt metathesis reactions; characterized by multielement NMR, IR spectroscopy, and single-crystal X-ray diffraction.

Freshness

Last updated 2026-04-23 19:36:07.