Data for Expanding Reactivity of Masked Divalent Lanthanide-Isocarbonyl Complexes

7.3 MB of experimental data supporting a 2026 paper in Organometallics. The dataset includes CIF files, IR and NMR spectroscopy data, and magnetic measurements for synthesized gadolinium, lutetium, and dysprosium isocarbonyl complexes. It was authored by Siobhan Temple and published on figshare.

Use Cases

• Validate crystal structures of lanthanide complexes based on provided CIF files.
• Analyze bonding and electronic structure based on IR spectroscopy data for isocarbonyl back-bonding.
• Study magnetic relaxation properties based on magnetic measurement data for gadolinium and dysprosium analogues.

Strengths

• Data is directly linked to a peer-reviewed publication in Organometallics (2026, 45, 7, 885–891).
• Includes multiple complementary data types: crystallographic, spectroscopic, and magnetic.
• Released under a permissive CC-BY-4.0 license.

Limitations

• Row count and column-level documentation are unknown, which may limit suitability assessment.
• Description metadata is limited; actual data quality requires manual inspection after download.

Provenance

Source

figshare, authored by Siobhan Temple.

Collection Method

Experimental data generated for synthetic chemistry research.

Freshness

Last updated 2026-04-16 08:41:11.