Kinetic Models for Methanol Synthesis Under Product Removal Conditions

An experimental study evaluates kinetic models for methanol synthesis from CO2 and H2 under conditions of water and methanol depletion. The dataset, authored by F. Bihl and last updated in June 2026, assesses models by Graaf, Park, Seidel, and Slotboom across temperatures of 210–270 °C and pressures of 23–46 bar. It comprises a 719.6 KB document analyzing model performance for sorption-enhanced reactor applications.

Use Cases

• Validating kinetic models for methanol synthesis based on experimental data under product-depleting conditions.
• Comparing the predictive capabilities of Graaf, Seidel, and Slotboom models based on pressure variation tests.
• Supporting the design of sorption-enhanced or membrane reactors based on kinetic parameter fitting at 33 bar.
• Benchmarking new kinetic models against established ones using data from a temperature range of 210–270 °C.

Strengths

• Data covers a defined experimental range of 210–270 °C and 23–46 bar.
• Explicitly evaluates four established kinetic models (Graaf, Park, Seidel, Slotboom).
• Results include specific pressure points (33 bar) where satisfactory fitting was achieved.

Limitations

• Dataset scope is limited to a 719.6 KB document; raw experimental data is not provided.
• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment for large-scale ML tasks.

Provenance

Source

figshare

Collection Method

Experimental study conducted under lab conditions.

Freshness

Last updated 2026-06-01 05:36:26; freshness should be verified.