Ni(II) Coordination Polymer: Synthesis, Structure, and Catalytic Dye Reduction Data

A research paper by Sukanya Paul, published on figshare in April 2026, details the synthesis and analysis of a nickel-based coordination polymer. The study includes structural characterization via single-crystal diffraction, thermal stability analysis, Density Functional Theory (DFT) computations predicting a 1.4 eV energy gap, and catalytic performance data for reducing methyl orange and methylene blue dyes. The polymer demonstrated catalytic rate constants of 0.415 min⁻¹ and 0.26 min⁻¹ for the respective dyes and maintained conversion rates above 82% after four reuse cycles.

Use Cases

• Benchmarking catalytic performance for organic dye reduction based on the reported rate constants and reuse cycle data.
• Validating DFT computational models for coordination polymers based on the reported 1.4 eV energy gap.
• Analyzing thermal decomposition pathways of coordination polymers based on the thermogravimetric analysis (TGA) results.
• Studying the relationship between 3D framework structure and catalytic activity based on the single-crystal diffraction analysis.

Strengths

• Includes specific catalytic performance metrics: rate constants of 0.415 min⁻¹ (methyl orange) and 0.26 min⁻¹ (methylene blue).
• Reports material reusability data: conversion rates remained at 84.97% and 82% after four cycles.
• Provides a theoretical energy gap value (1.4 eV) from Density Functional Theory (DFT) computations.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.
• The primary data format is a DOCX file, which may require extraction or conversion for computational analysis.

Provenance

Source

figshare

Collection Method

Synthesized and characterized in a laboratory setting; data reported in a research paper.

Time Range

The study was published in 2026; experimental timeframe is not specified.

Freshness

Last updated 2026-04-11 20:23:24; freshness should be verified.

Geography

Spatial coverage is not specified.