Electrochemical Sulfenamide Synthesis Data with High Atom Economy

A novel, transition metal- and oxidant-free electrochemical method for synthesizing sulfenamides with high atom economy (84.1%). The dataset, authored by Xiujuan Zhang and last updated in March 2026, likely contains experimental results from reactions conducted under constant current, mild conditions (50 °C, air atmosphere).

Use Cases

• Modeling reaction yields based on substrate scope and functional group tolerance described in the protocol.
• Analyzing the efficiency of the electrochemical method based on reported atom economy (84.1%).
• Comparing synthetic outcomes under the described mild conditions (50 °C, air atmosphere).
• Investigating the practical utility of the method based on the described gram-scale synthesis.

Strengths

• Reported high atom economy of 84.1% for the synthesis method.
• Reactions conducted under mild, specified conditions of 50 °C in an air atmosphere.
• Gram-scale synthesis and preliminary mechanistic studies are presented, indicating practical utility.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.
• Data may reflect methodological bias inherent to the single experimental protocol.

Provenance

Source

figshare

Collection Method

Experimental data from a novel electrochemical synthesis protocol.

Freshness

Last updated 2026-03-19 06:03:32; freshness should be verified.