A dataset from e-cienciaDatos Harvested Dataverse contains catalytic performance data for enantiopure zinc-scorpionate complexes. It includes results for ring-opening polymerization of rac-lactide, CO2 fixation into cyclic carbonates, and synthesis of polycarbonates, along with selected structural bond lengths and angles. Author Marta Navarro last updated the dataset on 2025-10-14.
Use Cases
- Benchmarking catalyst performance for polylactide synthesis based on reported isoselectivity (Pi = 0.88) and mild conditions.
- Evaluating catalyst activity for CO2 fixation into epoxides based on reported turnover frequencies (TOF = 227 h−1) and substrate scope.
- Analyzing catalyst selectivity for polycarbonate synthesis based on reported narrow dispersity values under soft conditions.
- Correlating catalyst structure with activity based on provided bond lengths and angles from X-ray diffraction studies.
Strengths
- Includes specific quantitative performance metrics, such as an isoselectivity value of Pi = 0.88 for polylactide synthesis.
- Reports concrete catalytic activity with a turnover frequency (TOF) of 227 h−1 for CO2 fixation.
- Contains selected structural data (bond lengths and angles) for catalyst characterization.
Limitations
- Column-level documentation is absent; field semantics must be inferred after download.
- Row count is unknown, which may limit suitability assessment.
Provenance
- Source
- e-cienciaDatos Harvested Dataverse
- Collection Method
- Experimental catalytic data and structural measurements from X-ray diffraction studies.
- Time Range
- null
- Freshness
- Last updated 2025-10-14 21:47:00; freshness should be verified.
- Geography
- null