Heterometallic Pyrazolate Bridge Complexes [PhenPd_x(μ-dmpz)_nM(OOCR)<

Five heterometallic pyrazolate-bridged complexes were synthesized and characterized by Marina A. Uvarova. The dataset includes CIF files containing X-ray diffraction data, with Pd···M distances ranging from 3.213–3.468 Å. These findings provide a rational synthetic approach for designing heterometallic assemblies with specific compositions and nuclearities.

Use Cases

• Training models to predict metal-metal distances in heterometallic complexes based on crystallographic data.
• Analyzing structural trends in square-planar vs. tetrahedral metal environments from diffraction data.
• Developing synthetic design rules for heterometallic assemblies based on composition and nuclearity.

Strengths

• Data is derived from multiple characterization techniques: X-ray diffraction, FT-IR, ESI-Mass Spectrometry, NMR, and elemental analysis.
• Specific structural details are provided, such as Pd···M distances ranging from 3.213–3.468 Å.
• The dataset contains CIF files, a standard format for crystallographic information.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.

Provenance

Source

figshare

Collection Method

Synthesized and characterized in a laboratory setting.

Time Range

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Freshness

Last updated 2026-05-01 12:04:45; freshness should be verified.

Geography

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