Heterometallic Pyrazolate Bridge Complexes [PhenPd_x(μ-dmpz)_nM(OOCR)<

A series of heterometallic binuclear and trinuclear 1,10-phenanthroline-based complexes, synthesized and characterized by Marina A. Uvarova. The dataset includes structural data from X-ray diffraction, FT-IR spectroscopy, ESI-Mass Spectrometry, NMR spectroscopy, and elemental analysis, with nonbinding Pd···M distances ranging from 3.213–3.468 Å. The data was last updated on 2026-05-01.

Use Cases

• Analyzing metal-metal distances and coordination geometries based on X-ray diffraction data.
• Validating the integrity of heterometallic complexes in solution using mass spectrometry data.
• Studying synthetic approaches for designing assemblies with specific compositions and nuclearities.
• Comparing spectroscopic signatures (FT-IR, NMR) across different metal centers (Co, Cu, Zn).

Strengths

• Includes data from multiple characterization techniques: X-ray diffraction, FT-IR, ESI-MS, NMR, and elemental analysis.
• Reports specific structural metrics, such as nonbinding Pd···M distances ranging from 3.213–3.468 Å.
• Describes a rational synthetic approach for heterometallic assemblies with controlled nuclearities.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• The dataset is small (874.1 KB), indicating a limited scope of experimental results.

Provenance

Source

figshare

Collection Method

Synthetic chemistry experiments with subsequent characterization by multiple analytical techniques.

Time Range

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Freshness

Last updated 2026-05-01 12:04:43; freshness should be verified.

Geography

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