Hierarchically Porous Zr-Based MOF Monolith Synthesis Data

Thomas E. Anthony published a dataset on figshare in May 2026 describing a synthesis strategy for hierarchically porous zirconium-based metal–organic framework monoliths. The dataset likely contains experimental parameters and results for the coordination replication method using sacrificial templates. The ZIP file is 32.6 KB.

Use Cases

• Optimizing synthesis conditions based on reaction temperature, time, and modulator concentration parameters
• Analyzing pore size distribution tunability based on reaction conditions and parent monolith features
• Evaluating catalytic activity preservation based on model Knoevenagel reaction and kinetic adsorption studies

Strengths

• The dataset describes a synthesis method applicable to a range of 12-connected Zr-based MOFs, including UiO-66 and -67 topologies.
• The approach is described as robust enough to accommodate various linker functionalities and lengths.
• The dataset includes a systematic investigation of factors influencing conversion, such as temperature, time, and modulator concentration.

Limitations

• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.
• The dataset is very small (32.6 KB), suggesting limited scope or a preliminary dataset.

Provenance

Source

Thomas E. Anthony via figshare

Collection Method

Experimental synthesis using the coordination replication method with zirconium oxy/hydroxide gel sacrificial templates.

Freshness

Last updated 2026-05-05 15:43:26; freshness should be verified.