FeL1-Cl: Molecular Oxygen Reduction Catalysis Data with Cation Effects

Modular crown–porphyrin architectures incorporating redox-inactive cations enable systematic modulation of local electric fields. The dataset, authored by Hwi Yul Jo and last updated in April 2026, likely contains spectroscopic and electrochemical analyses of iron complexes. It provides a framework for designing cation-responsive molecular architectures for catalytic outcomes.

Use Cases

• Analyzing charge-dependent perturbations in catalytic activity based on mono-, di-, and tri-valent cations.
• Modeling the interplay of electrostatic and Lewis acid effects on oxygen reduction catalysis.
• Training predictive models for catalyst reactivity landscapes based on spectroscopic and electrochemical data.
• Benchmarking design principles for cation-responsive molecular architectures.

Strengths

• Data is derived from a modular and programmable secondary coordination environment design.
• The dataset is licensed under CC-BY-NC-4.0, allowing for non-commercial reuse with attribution.
• Last updated on 2026-04-13, indicating recent curation.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• The dataset is 503.9 KB, indicating a very limited scope.

Provenance

Source

figshare

Collection Method

Likely contains experimental spectroscopic and electrochemical analyses.

Time Range

null

Freshness

Last updated 2026-04-13 04:33:29.

Geography

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