Al/Cr Heterobimetallic Complex Reactivity with Epoxides

A dataset from figshare describes the reactivity of a cyclopentadienyl-containing Al/Cr heterobimetallic isocarbonyl complex with epoxides. The data, authored by Roushan Prakash Singh and last updated in May 2026, defines a new mode of Cp functionalization and clarifies decomposition pathways for CpCr(CO)3R complexes. The dataset is small, with a file size of 72.2 KB.

Use Cases

• Modeling frustrated Lewis pair reactivity based on the described Al/Cr complex
• Studying radical cyclopentadienyl functionalization pathways based on the described reaction with propylene oxide
• Analyzing β-hydride elimination pathways based on the described reaction with styrene oxide
• Benchmarking computational methods for heterobimetallic platform behavior

Strengths

• File size is precisely 72.2 KB, indicating a focused dataset.
• Last update date is explicitly provided as 2026-05-16.
• Author attribution is clearly stated as Roushan Prakash Singh.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• The dataset's small size of 72.2 KB suggests a very limited scope.

Provenance

Source

figshare

Freshness

Last updated 2026-05-16 14:15:48; freshness should be verified.