Pyridylalkenolato-Stabilized Heavier Tetrylenes: Air-Stability and Coordination Chemistry

A 62.4 KB dataset from figshare examines the air and water stability of heavier tetrylenes synthesized using a specific precursor. Sergio García-Vega published this research on 2026-05-18, which includes DFT calculations and preliminary coordination studies with iridium, gold, and silver complexes. The analysis shows these compounds undergo hydrolysis at room temperature, with stability varying significantly between germanium and tin derivatives.

Use Cases

• Modeling hydrolytic degradation pathways based on DFT calculations mentioned in the description
• Comparing air-stability trends between germanium and tin tetrylenes as described
• Studying coordination chemistry outcomes with iridium, gold, and silver precursors as detailed
• Analyzing the reactivity differences between homoleptic and heteroleptic tetrylene compounds

Strengths

• Dataset is focused on a specific, novel chemical precursor (3,3,3-trifluoro-1-(2-pyridyl)prop-1-en-2-ol) for synthesizing heavier tetrylenes
• Includes analysis of both previously reported and novel heteroleptic chloro-heavier tetrylenes
• Combines experimental stability studies with DFT calculations to propose reaction mechanisms

Limitations

• Description metadata is limited; actual data quality requires manual inspection after download
• Column-level documentation is absent; field semantics must be inferred after download
• Row count is unknown, which may limit suitability assessment

Provenance

Source

Sergio García-Vega via figshare

Collection Method

Likely contains experimental and computational chemistry data from synthesis, stability testing, and coordination studies.

Freshness

Last updated 2026-05-18 06:45:19; freshness should be verified