Rhenium-Tin Bimetallic Nitrido Complex Synthesis and Reactivity Data

5.1 KB of data from figshare details the synthesis and properties of a square planar rhenium(III)/tin(IV) bimetallic nitrido complex. Author James L. Scott published the dataset on 2026-05-15. The data likely contains structural and reactivity information for this complex, which was studied via X-ray crystallography and DFT calculations.

Use Cases

• Modeling catalytic cycles for N2 functionalization based on the described reduction and reoxidation sequence.
• Studying the properties of square planar rhenium(III) geometries based on the X-ray crystallography data.
• Investigating radical reduction pathways in inorganic synthesis based on the mechanistic studies involving radical initiators.
• Benchmarking DFT calculations for bimetallic complexes based on the structural data for [ReIII(PNP)(N)·Sn(Bu)3(Cl)].

Strengths

• Data is associated with a peer-reviewed scientific publication, suggesting a high level of curation.
• The dataset includes results from multiple analytical techniques, including X-ray crystallography and DFT calculations.
• The description provides specific chemical names and reaction pathways, indicating detailed contextual metadata.

Limitations

• The dataset is very small at 5.1 KB, indicating limited scope.
• Column-level documentation is absent; field semantics must be inferred after download.
• Row count is unknown, which may limit suitability assessment.

Provenance

Source

figshare

Collection Method

Likely generated from laboratory synthesis, characterization, and computational studies.

Freshness

Last updated 2026-05-15 02:03:28; freshness should be verified.