Redox Chemistry and Photophysics of the V(dgpy)2 Redox Pair

Experimental and computational data elucidate the redox and photostability of earth-abundant vanadium complexes. The dataset combines quantum chemistry with results from cyclic voltammetry, spectroelectrochemistry, and ultrafast transient absorption spectroscopy. Alexandra König published this 35.2 KB dataset under a CC-BY-NC-4.0 license in 2026.

Use Cases

• Modeling excited-state lifetimes based on ground-state splitting and spin-flip state mixing described in the study
• Analyzing redox stability using cyclic voltammetry and spectroelectrochemistry data
• Investigating photophysical pathways from collision-induced dissociation and ultraviolet photodissociation mass spectrometry results
• Benchmarking quantum chemistry calculations against experimental structural and spectroscopic data

Strengths

• Dataset integrates multiple experimental techniques (cyclic voltammetry, mass spectrometry, transient absorption spectroscopy) with quantum chemistry.
• Focuses on earth-abundant vanadium complexes, a topic of significant potential for sustainable photochemistry.
• Published under a clear CC-BY-NC-4.0 license with author attribution.

Limitations

• Dataset size is only 35.2 KB, indicating a very limited scope.
• Row count and column-level documentation are unknown, complicating suitability assessment.
• Description metadata is limited; actual data quality requires manual inspection after download.

Provenance

Source

figshare

Collection Method

Combined quantum chemistry calculations with experimental data collection.

Freshness

Last updated 2026-05-23 20:03:26