Redox Switching of Magnetic Anisotropy in Copper Verdazyl Complexes

Connie Chi published data on figshare in April 2026 detailing the synthesis and properties of copper(II) verdazyl complexes. The dataset includes experimental and computational results for three redox states, with specific zero-field splitting parameters measured via high-frequency EPR. The file size is 4.3 KB, indicating a limited scope focused on molecular property data.

Use Cases

• Modeling magnetic anisotropy based on reported zero-field splitting parameters (D, E/D).
• Benchmarking DFT calculations against experimental EPR data for copper complexes.
• Studying redox-induced changes in molecular properties based on the described one-electron oxidation steps.
• Analyzing the relationship between Jahn-Teller distortion and magnetic anisotropy as suggested in the description.

Strengths

• Includes specific, quantitative parameters for zero-field splitting (D = 4.5 cm⁻¹ and 1.5 cm⁻¹).
• Covers three distinct redox states of the same molecular complex.
• Combines experimental (HF-EPR) and computational (DFT) data points.

Limitations

• Row count is unknown, which may limit suitability assessment.
• Column-level documentation is absent; field semantics must be inferred after download.
• The dataset is very small (4.3 KB), indicating limited scope.

Provenance

Source

figshare, author Connie Chi

Collection Method

Likely contains synthesized experimental and computational chemistry data.

Time Range

null

Freshness

Last updated 2026-04-09 23:44:29; freshness should be verified.

Geography

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