Catalytic data from a 2025 study describes zinc-based catalysts for the ring-opening copolymerization of CO₂ and cyclohexene oxide. The dataset includes key polymerization parameters such as reaction time, pressure, temperature, turnover frequency, and selectivity. It contains results from the accompanying manuscript, including catalyst screening and optimization data for producing poly(cyclohexene carbonate) and poly(L-lactide)-b-polycarbonate hybrid materials.
Use Cases
- Benchmarking catalyst performance based on reported turnover frequency and selectivity data.
- Modeling the relationship between catalyst structure and polymerization outcomes based on described electron-withdrawing group effects.
- Analyzing the influence of reaction conditions on CO2 incorporation levels based on temperature, pressure, and monomer feed data.
- Studying thermal properties of hybrid polymers based on reported glass transition temperatures and stability up to 240 °C.
Strengths
- Includes data from both literature review and original experiments described in a 2025 manuscript.
- Reports specific thermal properties, such as glass transition temperatures around 60 °C and stability up to 240 °C.
- Catalytic data covers multiple parameters including time, pressure, temperature, and selectivity.
Limitations
- Column-level documentation is absent; field semantics must be inferred after download.
- Row count is unknown, which may limit suitability assessment.
- Description metadata is limited; actual data quality requires manual inspection after download.
Provenance
- Source
- e-cienciaDatos Harvested Dataverse, author Marta Navarro.
- Collection Method
- Likely contains experimental results from polymerization studies and compiled literature data.
- Time Range
- null
- Freshness
- Last updated 2025-10-14 21:44:58; freshness should be verified.
- Geography
- null