Cd-Based Coordination Polymers with Substituent-Modulated Fluorescence Properties

Three isostructural, one-dimensional cadmium-based coordination polymers were hydrothermally synthesized via systematic substituent modification. Their solid-state fluorescence is precisely regulated by electronic and steric effects, enabling dual-channel emission and distinct thermoresponsive and mechanoresponsive behaviors. The dataset, authored by Shuyu Wang and last updated in April 2026, is a 404.6 KB collection of CIF files detailing these structures and properties.

Use Cases

• Modeling structure-property relationships based on substituent-induced structural subtlety.
• Developing sensor materials based on described thermoresponsive fluorescence behaviors.
• Designing optoelectronic materials based on tunable dual-channel fluorescence.
• Studying excimer-derived fluorescence in coordination polymers based on substituent engineering.

Strengths

• Data includes three distinct, rationally designed isostructural compounds for comparative analysis.
• Fluorescence properties are characterized for dual-channel emission and stimulus-responsive behaviors.
• Dataset is focused on a specific, well-defined chemical system for structure-property study.

Limitations

• Dataset is small, with a total size of 404.6 KB, indicating limited scope.
• Row count and column-level documentation are unknown, requiring manual inspection after download.
• Description metadata is limited; actual data quality requires manual inspection after download.

Provenance

Source

figshare

Collection Method

Hydrothermal synthesis and systematic substituent modification, as described.

Freshness

Last updated 2026-04-15 20:44:33; freshness should be verified.